Photocatalytic degradation of naphthalene and anthracene: GC-MS analysis of the degradation pathway

被引：100

作者：

Theurich, J ^{[1
]}

Bahnemann, DW ^{[1
]}

Vogel, R ^{[1
]}

Ehamed, FE ^{[1
]}

Alhakimi, G ^{[1
]}

Rajab, I ^{[1
]}

机构：

[1] RAS LANUF OIL & GAS PROC CO INC, TRIPOLI, LIBYA

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 1997年 / 23卷 / 03期

关键词：

D O I：

10.1163/156856797X00457

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mechanism of the photocatalytic transformation of naphthalene and anthracene has been studied qualitatively in aqueous suspensions of titanium dioxide under UV-irradiation. The degradation products were identified by GC-MS technique. 15 different intermediates have been identified during the photocatalytic degradation of naphthalene. A detailed reaction mechanism is proposed to explain their formation. For the photocatalytic degradation of anthracene phthalic acid and 9,10-anthraquinone have been found as relatively stable intermediates. Their photocatalytic degradation has been followed in separate experiments to achieve further clarification of the reaction pathway.

引用

页码：247 / 274

页数：28

共 65 条

[1]

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