Direct synthesis of seven- and eight-membered lactones by ruthenium-catalyzed cyclocarbonylation of allenyl alcohols

被引：33

作者：

Yoneda, E ^{[1
]}

Zhang, SW ^{[1
]}

Onitsuka, K ^{[1
]}

Takahashi, S ^{[1
]}

机构：

[1] Osaka Univ, Inst Sci & Ind Res, Ibaraki, Osaka 5670047, Japan

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 32期

基金：

日本学术振兴会;

关键词：

carbonylation; lactones; allenyl alcohols; cyclization; ruthenium catalyst;

D O I：

10.1016/S0040-4039(01)01018-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Carbonylation of 6-hydroxyhexa-1,2-dienes and 7-hydroxyhepta-1,2-dienes with a ruthenium catalyst in triethylamine quantitatively gave seven- and eight-membered lactones, respectively, in which the hydroxyl group of allenyl alcohols participated in the cyclization. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：5459 / 5461

页数：3

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