Novel chemotaxonomic markers of the Alternaria infectoria species-group

被引:49
作者
Christensen, KB
Van Klink, JW
Weavers, RT
Larsen, TO
Andersen, B
Phipps, RK
机构
[1] Tech Univ Denmark, Ctr Microbial Biotechnol, Bioctr, DK-2800 Lyngby, Denmark
[2] Univ Otago, Dept Chem, Dunedin, New Zealand
[3] New Zealand Inst Crop & Food Res Ltd, Plant Extracts Res Unit, Dunedin, New Zealand
关键词
Alternaria; chemotaxonomy; alpha-pyrone; infectopyrone; novae-zelandin; phytotoxin;
D O I
10.1021/jf0513213
中图分类号
S [农业科学];
学科分类号
09 [农学];
摘要
Two new structurally related metabolites, novae-zelandin A (1) and novae-zelandin B (2), as well as the novel metabolite 4Z-infectopyrone (3) were purified from extracts of filamentous fungi belonging to the Alternaria infectoria species-group. The structures were elucidated by a combination of 1 D and 2D NMR spectroscopic data and MS data. 1-3 are important chemotaxonomic markers of the A. infectoria species-group and exhibit structures similar to those of known biologically active compounds, suggesting that they could be potential phytotoxins.
引用
收藏
页码:9431 / 9435
页数:5
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