Formation of small-diameter carbon nanotubes from PTCDA arranged inside the single-wall carbon nanotubes

被引:48
作者
Fujita, Y [1 ]
Bandow, S [1 ]
Iijima, S [1 ]
机构
[1] Meijo Univ, Dept Mat Sci & Engn Elect & Elect Engn, Century COE 21, Nagoya, Aichi 4688502, Japan
关键词
D O I
10.1016/j.cplett.2005.08.033
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A systematic study was carried out on the doping of perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA) to the single-wall carbon nanotubes (SWNTs). After the doping reaction, the interior space of SWNTs was fully filled with the dopant. The heat treatment at high temperature in vacuum of this PTCDA-filled SWNTs induced new Raman signals ranging between 300 and 400 cm(-1), which was assigned to the radial breathing mode of vibration associated with the inner tubes. Furthermore, transmission electron microscopy clearly showed the existence of one-dimensionally arranged PTCDA molecules in the tube and the secondary inner tubes formed after the high-temperature treatment. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:410 / 414
页数:5
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