Methanol oxidation by pEDOT-pSS/PtRu in DMFC

Direct methanol fuel cells (DMFCs) are attracting more and more attention because of their operating temperature and easy fuel management. While carbons are the most widely used supports for both metal catalysts, i.e. PtRu for methanol oxidation and Pt for oxygen reduction, conducting polymers also can act as suitable supports for catalyst particles because of their conductive and stable three-dimensional structure. We thus chemically synthesized poly(3,4-ethylenedioxythiophene)-polystyrene-4-sulfonate (pEDOT-pSS) with different (3,4-ethylenedioxythiophene):styrene-4-sulfonate (EDOT:SS) molar ratios and prepared the electrocatalytic systems pEDOT-pSS/PtRu and pEDOT-pSS/Pt, the former by both electrochemical and chemical deposition of PtRu and the latter by chemical deposition of Pt. The results of the electrocatalytic activity tests of the pEDOT-pSS/PtRu composite electrodes performed in 0.1 M H2SO4-0.5 M CH3OH liquid solution and in passive, air-breathing DMFC configuration with Nafion (R) 115 protonic membrane and 1 M CH3OH are reported and discussed. (C) 2007 Elsevier B.V. All rights reserved.