Cephalotoside A:: a tridesmosidic cycloartane type glycoside from Astragalus cephalotes var. brevicalyx

被引：26

作者：

Calis, I ^{[1
]}

Yusufoglu, H

Zerbe, O

Sticher, O

机构：

[1] Hacettepe Univ, Fac Pharm, Dept Pharmacognosy, TR-06100 Ankara, Turkey

[2] ETH Zurich, Swiss Fed Inst Technol, Dept Pharm, CH-8057 Zurich, Switzerland

来源：

PHYTOCHEMISTRY | 1999年 / 50卷 / 05期

关键词：

Astragalus cephalotes var. brevicalyx; Leguminosae; cycloartane glycosides; cephalotoside A; cyclocanthosides A; D; E;

D O I：

10.1016/S0031-9422(98)00601-3

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 [生物化学与分子生物学]; 081704 [应用化学];

摘要：

A new tridesmosidic cycloartane type glycoside, cephalotoside A was isolated from the roots of Astragahus cephalotes var. brevicalyx in addition to the known glycosides cyclocanthosides A, D and E. The structure of the new compound was determined by spectral (IR, H-1- and C-13-NMR, and FABMS) and chemical (acetylation) methods and established as 3 beta-(beta-D-xylopyranosyl)oxy-16 beta-(beta-D-glucopyranosyl)oxy-24- (beta-D-xylopyranosyl)oxy-cycloarlane-6 alpha,25-diol. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：843 / 847

页数：5

共 6 条

[1]

Cyclocephaloside I:: A novel cycloartane-type glycoside from Astragalus microcephalus [J].

Bedir, E ;

Calis, I ;

Zerbe, O ;

Sticher, O .

JOURNAL OF NATURAL PRODUCTS, 1998, 61 (04) :503-505

[2]

Cycloartane triterpene glycosides from the roots of Astragalus melanophrurius [J].

Calis, I ;

Yuruker, A ;

Tasdemir, D ;

Wright, AD ;

Sticher, O ;

Luo, YD ;

Pezzuto, JM .

PLANTA MEDICA, 1997, 63 (02) :183-186

[3]

Four novel cycloartane glycosides from Astragalus oleifolius [J].

Calis, I ;

Zor, M ;

Saracoglu, I ;

Isimer, A ;

Ruegger, H .

JOURNAL OF NATURAL PRODUCTS, 1996, 59 (11) :1019-1023

[4]

FADEEV YM, 1988, KHIM PRIR SOEDIN+, P73

[5]

FADEEV YM, 1987, KHIM PRIR SOEDIN+, P817

[6]

ISAEV MI, 1992, KHIM PRIR SOEDIN+, P360

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