Nickel nitride as negative electrode material for lithium ion batteries

被引：78

作者：

Gillot, Frederic ^{[1
]}

Oro-Sole, Judith ^{[1
]}

Rosa Palacin, M. ^{[1
]}

机构：

[1] CSIC, Inst Ciencia Mat Barcelona, E-08193 Bellaterra, Catalonia, Spain

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2011年 / 21卷 / 27期

关键词：

METAL NITRIDE; POTASSIUM-AMIDE; LIQUID-AMMONIA; ANODE MATERIAL; ELECTROCHEMISTRY; DIFFRACTION; MECHANISM; NI3N; NITROGEN; SYSTEM;

D O I：

10.1039/c0jm04144k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nickel nitride has been prepared through different routes involving ammonolysis of different precursors (Ni(NH(3))(6)Br(2) or nickel nanoparticles obtained from the reduction of nickel nitrate with hydrazine) and thermal decomposition of nickel amide obtained by precipitation in liquid ammonia. The electrochemical behavior against lithium was tested in all cases, the specific capacity being much larger for the latter (1200 mA h g(-1) compared to 85 mA h g(-1) and 125 mA h g(-1) respectively). Ni(3)N 'cast' electrodes exhibited good rate capability, with 500 mA h g(-1) reversible capacity maintained after 10 cycles at a rate of 1 Li per h.

引用

页码：9997 / 10002

页数：6

共 37 条

[1] Thin-film lithium and lithium-ion batteries [J].

Bates, JB ;

Dudney, NJ ;

Neudecker, B ;

Ueda, A ;

Evans, CD .

SOLID STATE IONICS, 2000, 135 (1-4) :33-45

[2] 6Li MAS NMR Investigation of Electrochemical Lithiation of RuO2: Evidence for an Interfacial Storage Mechanism [J].

Bekaert, Emilie ;

Balaya, Palani ;

Murugavel, Sevi ;

Maier, Joachim ;

Menetrier, Michel .

CHEMISTRY OF MATERIALS, 2009, 21 (05) :856-861

[3]

BOCH J, 1988, J LESS-COMMON MET, V137, P105

[4] Reactions between potassium amide and certain salts of cadmium, nickel and chromium in liquid ammonia solution [J].

Bohart, GS .

JOURNAL OF PHYSICAL CHEMISTRY, 1915, 19 (07) :537-563

[5]

BOHART GS, 1914, J PHYS CHEM-US, V19, P537

[6] Towards new negative electrode materials for Li-ion batteries:: Electrochemical properties of LiNiN [J].

Cabana, Jordi ;

Stoeva, Zlatka ;

Titman, Jeremy J. ;

Gregory, Duncan H. ;

Palacin, M. Rosa .

CHEMISTRY OF MATERIALS, 2008, 20 (05) :1676-1678

[7] Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions [J].

Cabana, Jordi ;

Monconduit, Laure ;

Larcher, Dominique ;

Rosa Palacin, M. .

ADVANCED MATERIALS, 2010, 22 (35) :E170-E192

[8] High rate performance of lithium manganese nitride and oxynitride as negative electrodes in lithium batteries [J].

Cabana, Jordi ;

Ionica-Bousquet, Costana M. ;

Grey, Clare P. ;

Palacin, M. Rosa .

ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (02) :315-318

[9] Nanoflake CoN as a high capacity anode for Li-ion batteries [J].

Das, B. ;

Reddy, M. V. ;

Malar, P. ;

Osipowicz, Thomas ;

Rao, G. V. Subba ;

Chowdari, B. V. R. .

SOLID STATE IONICS, 2009, 180 (17-19) :1061-1068

[10] Electrochemical reactions of lithium with transition metal nitride electrodes [J].

Fu, ZW ;

Wang, Y ;

Yue, XL ;

Zhao, SL ;

Qin, QZ .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (07) :2236-2244

← 1 2 3 4 →