Intergrowth between V2O5 and TiO2 (anatase): High resolution electron microscopy evidence

被引：26

作者：

Kryukova, GN ^{[1
]}

Klenov, DO ^{[1
]}

Zenkovets, GA ^{[1
]}

机构：

[1] NOVOSIBIRSK STATE UNIV,NOVOSIBIRSK 630090,RUSSIA

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1997年 / 60卷 / 01期

关键词：

Vanadia-titania catalysts; intergrowth; structure;

D O I：

10.1007/BF02477707

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

V2O5/TiO2 (anatase) with 5 and 20 wt% loadings of V2O5 have been studied using high resolution electron microscopy. This has provided the first direct evidence for the formation of a coherent interfacial boundary between two crystalline TiO2 and V2O5 phases. The type of the interfacial stacking was found to be similar for all the samples, whereas the length of the boundary formed depended on the V2O5 loading. A model for the atomic arrangement of this boundary based on a comparison of structural positions of oxygen and metal atoms in the crystal lattices of both phases is proposed.

引用

页码：179 / 187

页数：9

共 13 条

[1] AN INFRARED AND ELECTRICAL CONDUCTANCE STUDY OF V2O5/SIO2-TIO2 CATALYSTS ACTIVE FOR THE REDUCTION OF NO BY NH3
BJORKLUND, RB
ODENBRAND, CUI
BRANDIN, JGM
ANDERSSON, LAH
LIEDBERG, B
[J]. JOURNAL OF CATALYSIS, 1989, 119 (01) : 187 - 200
[2] MECHANISM OF THE OXIDATION OF ORTHO-XYLENE TO PHTHALIC-ANHYDRIDE
BOND, GC
[J]. JOURNAL OF CATALYSIS, 1989, 116 (02) : 531 - 539
[3] CRISTIANI C, 1989, J CATAL, V116, P584
[4] SOLID-STATE V-15 NMR STRUCTURAL STUDIES ON SUPPORTED VANADIUM(V) OXIDE CATALYSTS - VANADIUM-OXIDE SURFACE-LAYERS ON ALUMINA AND TITANIA SUPPORTS
ECKERT, H
WACHS, IE
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (18) : 6796 - 6805
[5] ELECTRICAL-CONDUCTIVITY CHARACTERIZATION OF EUROCAT TITANIA-SUPPORTED VANADIA CATALYSTS
HERRMANN, JM
DISDIER, J
[J]. CATALYSIS TODAY, 1994, 20 (01) : 135 - 152
[6] *JCPDS, 40477 JCPDS
[7] *JCPDS, 9387 JCPDS
[8] AN IR SPECTROSCOPY STUDY OF THE STATE AND LOCALIZATION OF VANADIUM OXO SPECIES ADSORBED ON TIO2 (ANATASE)
KANTCHEVA, MM
HADJIIVANOV, KI
KLISSURSKI, DG
[J]. JOURNAL OF CATALYSIS, 1992, 134 (01) : 299 - 310
[9] SANTI M, 1990, J MOL CATAL, V53, P233
[10] TEM STUDY OF INTERFACIAL RELATIONSHIPS IN THE V2O5-TIO2(ANATASE) SYSTEM
VEJUX, A
COURTINE, P
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1986, 63 (02) : 179 - 190

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