Synthesis, characterization, and formation mechanism of copper sulfide-core/carbon-sheath cables by a simple hydrothermal route

被引：40

作者：

Chen, Guang-Yi ^{[2
]}

Deng, Bin ^{[1
]}

Cai, Guo-Bin ^{[1
]}

Dong, Wen-Fei ^{[2
]}

Zhang, Wan-Xi ^{[2
]}

Xu, An-Wu ^{[1
]}

机构：

[1] Univ Sci & Technol China, Div Nanomat & Chem, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China

[2] Jilin Univ, Coll Mat Sci & Engn, Changchun 130025, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2008年 / 8卷 / 07期

关键词：

D O I：

10.1021/cg701043f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper sulfide-core/carbon-shell cables and spheres have been prepared by a simple hydrothermal method. The obtained CuS/C cables and spheres were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, Raman, Fourier transform infrared spectroscopy, photoluminescence, and UV-vis-NIR spectrum analysis. The resulting CuS/C cables and spheres were obtained by a hydrothermal process in the presence of beta-cyclodextrin (beta-CD) acting as the ligand and the carbon source of the sheath. The influence of the reaction time, reaction temperature, different sulfur source, and different solution system on the final products was investigated in detail. The possible formation mechanism for these copper sulfide-core/carbon-shell cables was also proposed. Moreover, by using hot hydrochloric acid to dissolve the CuS cores, amorphous carbon nanotubes and hollow nanospheres can be obtained..

引用

页码：2137 / 2143

页数：7

共 66 条

[1] Nanotubes from carbon [J].

Ajayan, PM .

CHEMICAL REVIEWS, 1999, 99 (07) :1787-1799

[2] The formation of Cu2S from the elements I.: Copper used in form of powders [J].

Blachnik, R ;

Müller, A .

THERMOCHIMICA ACTA, 2000, 361 (1-2) :31-52

[3] Crystal structure of [Cu4(tu)7](SO4)2]•H2O and vibrational spectroscopic studies of some copper(I) thiourea complexes [J].

Bott, RC ;

Bowmaker, GA ;

Davis, CA ;

Hope, GA ;

Jones, BE .

INORGANIC CHEMISTRY, 1998, 37 (04) :651-657

[4] Chemistry and properties of nanocrystals of different shapes [J].

Burda, C ;

Chen, XB ;

Narayanan, R ;

El-Sayed, MA .

CHEMICAL REVIEWS, 2005, 105 (04) :1025-1102

[5] Kinetically controlled synthesis of wurtzite ZnS nanorods through mild thermolysis of a covalent organic-inorganic network [J].

Chen, XJ ;

Xu, HF ;

Xu, NS ;

Zhao, FH ;

Lin, WJ ;

Lin, G ;

Fu, YL ;

Huang, ZL ;

Wang, HZ ;

Wu, MM .

INORGANIC CHEMISTRY, 2003, 42 (09) :3100-3106

[6] Electrochemical behaviors of CuS as a cathode material for lithium secondary batteries [J].

Chung, JS ;

Sohn, HJ .

JOURNAL OF POWER SOURCES, 2002, 108 (1-2) :226-231

[7] The stability of cyclodextrin complexes in solution [J].

Connors, KA .

CHEMICAL REVIEWS, 1997, 97 (05) :1325-1357

[8] Synthesis of copper-core/carbon-sheath nanocables by a surfactant-assisted hydrothermal reduction/carbonization process [J].

Deng, Bin ;

Xu, An-Wu ;

Chen, Guang-Yi ;

Song, Rui-Qi ;

Chen, Liuping .

JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (24) :11711-11716

[9] Synthesis of polymer nanospheres and carbon nanospheres using the monomer 1,8-dihydroxymethyl-1,3,5,7-octatetrayne [J].

Ding, LH ;

Olesik, SV .

NANO LETTERS, 2004, 4 (11) :2271-2276

[10] Synthesis of CuS nanoparticles in water-in-carbon dioxide microemulsions [J].

Dong, X ;

Potter, D ;

Erkey, C .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2002, 41 (18) :4489-4493

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