Storage effect in LiRESiO4:Ce3+, Sm3+, RE = Y, Lu phosphor

被引:16
作者
Sidorenko, AV
Bos, AJJ
Dorenbos, P
van Eijk, CWE
Kahn-Harari, A
Rodnyi, PA
Viana, B
机构
[1] Delft Univ Technol, Interfac Reactor Inst, NL-2629 JB Delft, Netherlands
[2] ENSCP, UMR 7574, Lab Chim Appl Etat Solide, F-75231 Paris 05, France
[3] State Politech Univ, St Petersburg 195251, Russia
关键词
cerium; samarium; storage phosphor; stimulated luminescence;
D O I
10.1016/j.nima.2004.07.239
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
Good storage properties after irradiation have been observed in doubly rare-earth-doped LiRESiO4:Ce3+, Sm3+, RE= Y,Lu powders. We present strong arguments that in the studied materials Ce3+ ions play a role of hole trapping and Sm3+ ions of electron trapping centres. Additionally, oxygen vacancies are also involved in electron trapping. however they can be removed by appropriate thermal treatment. During thermal stimulation of irradiated LiRESiO4:Ce3+, Sm-3+,Sm- RE=Y.Lu an electron from Sm2+ is released into the conduction hand formed by SiO4 and further migrates to Ce4+ centers. This causes the TL peak at 340K in LiLuSiO4:Ce3+ Sm3+ and at 400K in LiySiO(4):Ce3+,Sm3+ upon heating rate of 1 Ks. Very fast and efficient photo-stimulated luminescence (PSL) have been observed upon stimulation with an IR laser (gimel = 830 nm). The presented materials can be utilized in Image Plates for X-ray or neutron position sensitive detection. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:81 / 85
页数:5
相关论文
共 6 条
[1]   CHARGE TRAPPING AND MECHANISM OF STIMULATED LUMINESCENCE IN CAS-CE,SM [J].
CHAKRABARTI, K ;
MATHUR, VK ;
THOMAS, LA ;
ABBUNDI, RJ .
JOURNAL OF APPLIED PHYSICS, 1989, 65 (05) :2021-2023
[2]   STIMULATED LUMINESCENCE IN RARE-EARTH-DOPED MGS [J].
CHAKRABARTI, K ;
MATHUR, VK ;
RHODES, JF ;
ABBUNDI, RJ .
JOURNAL OF APPLIED PHYSICS, 1988, 64 (03) :1363-1366
[3]  
DORENBOS P, IN PRESS J PHYS COND
[4]   CHARGE-TRANSFER ABSORPTION-BAND OF EU3+ IN OXIDES [J].
HOEFDRAAD, HE .
JOURNAL OF SOLID STATE CHEMISTRY, 1975, 15 (02) :175-177
[5]   STUDIES ON SOME INFRARED STIMULABLE PHOSPHORS [J].
KELLER, SP ;
MAPES, JE ;
CHEROFF, G .
PHYSICAL REVIEW, 1957, 108 (03) :663-676
[6]  
NAKAYAMA S, 1992, NIPPON SERAM KYO GAK, V100, P867, DOI 10.2109/jcersj.100.867