Imidazolylidene carbene ligated palladium catalysis of the Heck reaction in the presence of air

被引：35

作者：

Liu, JP

Zhao, YH

Zhou, YY

Li, L

Zhang, TY

Zhang, HB ^{[1
]}

机构：

[1] Yunnan Univ, Sch Pharm, Kunming 650091, Peoples R China

[2] Lilly Corp Ctr, Lilly Res Labs, Chem Proc Res & Dev, Indianapolis, IN 46285 USA

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2003年 / 1卷 / 18期

关键词：

D O I：

10.1039/b306715g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Five 1,3-disubstituted imidazolium salts were synthesized. Their Heck reaction activities were evaluated. A convenient, efficient and high yielding procedure based on these compounds for the arylation of olefins was developed. Heck reactions mediated by these palladium-N-heterocyclic carbene complexes were conducted under air and even in the presence of several common oxidants.

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页码：3227 / 3231

页数：5

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