Global rate expression for nitric oxide reburning .2.

被引：52

作者：

Chen, W ^{[1
]}

Smoot, LD ^{[1
]}

Hill, SC ^{[1
]}

Fletcher, TH ^{[1
]}

机构：

[1] BRIGHAM YOUNG UNIV,ADV COMBUST ENGN RES CTR,PROVO,UT 84602

来源：

ENERGY & FUELS | 1996年 / 10卷 / 05期

关键词：

D O I：

10.1021/ef960007v

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

An investigation of a global reburning-NO reaction, Sigma(ij)C(i)H(j) + NO --> HCN +..., which is a reduction pathway of nitric oxide (NO) by reaction with gaseous hydrocarbons, was conducted. The global reburning-NO rate expression was deduced from a combination of elemental reactions. The global rate expression and its rate constants were then determined by correlating predicted species profiles from simple hydrocarbon flames. This global reburning-NO rate constant can be expressed as 2.7 x 10(6) exp(-18 800/RT) (gmol/cm(3) s). This expression and constants are applicable to atmospheric pressure with an equivalence ratio range of 1.0-2.08 for light hydrocarbon reburning gases (CH4 and C2H4).

引用

页码：1046 / 1052

页数：7

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