Effect of donor number of solvent on the conductivity behaviour of nonaqueous proton-conducting polymer gel electrolytes

被引：57

作者：

Sekhon, SS ^{[1
]}

Arora, N ^{[1
]}

Singh, HP ^{[1
]}

机构：

[1] Guru Nanak Dev Univ, Dept Appl Phys, Amritsar 143005, Punjab, India

来源：

SOLID STATE IONICS | 2003年 / 160卷 / 3-4期

关键词：

polymer gel electrolytes; donor number; undissociated acid; proton conductors; carrier concentration;

D O I：

10.1016/S0167-2738(03)00167-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effect of donor number of solvent on the conductivity behaviour of gel electrolytes has been studied. Liquid electrolytes were prepared by dissolving salicylic acid in solvents based on ethylene carbonate (EC), propylene carbonate (PC) and dimethylformamide (DMF) with different donor number and dielectric constant values. Three different polymers, polymethylmethacrylate (PMMA), polyacrylonitrile (PAN) and polyethylene oxide (PEO), were used as the gelling polymer. The conductivity of polymer gel electrolytes has been found to be higher than the corresponding liquid electrolytes, i.e. sigma (gel)>sigma (liquid). This has been explained to be due to an increase in carrier concentration by the dissociation of undissociated salicylic acid/ion aggregates present in the electrolytes with the addition of polymer. However, the relative increase in conductivity observed with the addition of different gelling polymers has been found to depend upon the donor number of the solvent used. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：301 / 307

页数：7

共 24 条

[1] LI+-CONDUCTIVE SOLID POLYMER ELECTROLYTES WITH LIQUID-LIKE CONDUCTIVITY [J].

ABRAHAM, KM ;

ALAMGIR, M .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (05) :1657-1657

[2]

ABRAHAM KM, 1994, APPL ELECTROACTIVE P, P75

[3] GEL ELECTROLYTE FOR SOLID-STATE ELECTROCHROMIC CELL [J].

BOHNKE, O ;

ROUSSELOT, C ;

GILLET, PA ;

TRUCHE, C .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (07) :1862-1865

[4] FAST-ION TRANSPORT IN NEW LITHIUM ELECTROLYTES GELLED WITH PMMA .1. INFLUENCE OF POLYMER CONCENTRATION [J].

BOHNKE, O ;

FRAND, G ;

REZRAZI, M ;

ROUSSELOT, C ;

TRUCHE, C .

SOLID STATE IONICS, 1993, 66 (1-2) :97-104

[5] Structure and transport properties of polymer gel electrolytes based on PVdF-HFP and LiN(C2F5SO2)2 [J].

Capiglia, C ;

Saito, Y ;

Kataoka, H ;

Kodama, T ;

Quartarone, E ;

Mustarelli, P .

SOLID STATE IONICS, 2000, 131 (3-4) :291-299

[6] PMMA Based Protonic Polymer Gel Electrolytes [J].

Chandra, S. ;

Sekhon, S. S. ;

Arora, Narinder .

IONICS, 2000, 6 (1-2) :112-118

[7] All-polymeric electrochromic and photoelectrochemical devices: new advances [J].

De Paoli, MA ;

Nogueira, AF ;

Machado, DA ;

Longo, C .

ELECTROCHIMICA ACTA, 2001, 46 (26-27) :4243-4249

[8] Poly(methyl methacrylate)-based protonic gel electrolytes: a spectroscopic study [J].

Ericson, H ;

Svanberg, C ;

Brodin, A ;

Grillone, AM ;

Panero, S ;

Scrosati, B ;

Jacobsson, P .

ELECTROCHIMICA ACTA, 2000, 45 (8-9) :1409-1414

[9] ION-CONDUCTIVE MACROMOLECULAR GELS AND MEMBRANES FOR SOLID LITHIUM CELLS [J].

FEUILLADE, G ;

PERCHE, P .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1975, 5 (01) :63-69

[10] Proton polymeric gel electrolyte membranes based on polymethylmethacrylate [J].

Grillone, AM ;

Panero, S ;

Retamal, BA ;

Scrosati, B .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (01) :27-31

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