(2-Ethyl-5-oxo-hexyl) methylthiomethyl phthalate as by-product of the Swern oxidation:: Improved synthesis of ring-deuterated major metabolites of bis(2-ethylhexyl) phthalate

被引：10

作者：

Gilsing, HD ^{[1
]}

Angerer, J

Prescher, D

机构：

[1] Inst Dunnschichttechnol & Mikrosensorik EV, D-14513 Teltow, Germany

[2] Univ Erlangen Nurnberg, Inst & Poliklin Arbeits Sozial & Umweltmed, D-91054 Erlangen, Germany

来源：

MONATSHEFTE FUR CHEMIE | 2003年 / 134卷 / 09期

关键词：

bis(2-ethylhexyl) phthalate; metabolites; isotopic labelling; oxidations; methylthiomethyl esters;

D O I：

10.1007/s00706-003-0044-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two ring-deuterated major metabolites of bis(2-ethylhexyl) phthalate were obtained in excellent yields by means of an improved oxidation procedure. The by-product of their interconversion by Swern oxidation is elucidated and a possible mechanism of its formation is proposed.

引用

页码：1207 / 1213

页数：7

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