Modulation of a fluorescent switch based on a controllable photochromic diarylethene shutter

被引:35
作者
Chen, Y [1 ]
Xie, N [1 ]
机构
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100101, Peoples R China
关键词
D O I
10.1039/b506381g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A convenient system of modulation of a fluorescent switch based on photoisomerization of diarylethene has been demonstrated by employing 9,10-anthracenedinaphthalene 1 and benzothiazole diarylethene 2a as the fluorescence dye and the photochromic compound, respectively. The fluorescence change of 1 is modulated easily by photoisomerization of 2a, which is doped into the fluorescence dye, in solution as well as in a polymer film. The changes of fluorescence intensity of 1 between the ''on'' and ''off'' states are significant in both solution and polymer film and more than 20 cycles in solution and 10 cycles in polymer of fluorescence switching are achieved without distinguished change in fluorescence intensity.
引用
收藏
页码:3229 / 3232
页数:4
相关论文
共 38 条
[31]   Fluorescence modulation in polymer bilayers containing fluorescent and photochromic dopants [J].
Tomasulo, M ;
Giordani, S ;
Raymo, FM .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (05) :787-794
[32]   PHOTONIC MOLECULAR DEVICES - REVERSIBLY PHOTOSWITCHABLE FLUOROPHORES FOR NONDESTRUCTIVE READOUT FOR OPTICAL MEMORY [J].
TSIVGOULIS, GM ;
LEHN, JM .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (10) :1119-1122
[33]   Photoswitched and functionalized oligothiophenes: Synthesis and photochemical and electrochemical properties [J].
Tsivgoulis, GM ;
Lehn, JM .
CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (11) :1399-1406
[34]   Rational principles for modulating fluorescence properties of fluorescein [J].
Ueno, T ;
Urano, Y ;
Setsukinai, K ;
Takakusa, H ;
Kojima, H ;
Kikuchi, K ;
Ohkubo, K ;
Fukuzumi, S ;
Nagano, T .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (43) :14079-14085
[35]   Synthesis and characterization of 9-(cycloheptatrienylidene)fluorene derivatives: Acid-triggered "Switch on" of fluorophores [J].
Wang, ZX ;
Xing, YJ ;
Shao, HX ;
Lu, P ;
Weber, WP .
ORGANIC LETTERS, 2005, 7 (01) :87-90
[36]   A novel two-fluorophore approach to ratiometric sensing of Zn2+ [J].
Woodroofe, CC ;
Lippard, SJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (38) :11458-11459
[37]   Molecular switch based on a biologically important redox reaction [J].
Yan, P ;
Holman, MW ;
Robustelli, P ;
Chowdhury, A ;
Ishak, FI ;
Adams, DM .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (01) :130-137
[38]   Development of fluorescent film sensors for the detection of divalent copper [J].
Zheng, Y ;
Orbulescu, J ;
Ji, X ;
Andreopoulos, FM ;
Pham, SM ;
Leblanc, RM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (09) :2680-2686