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Singlet-oxygen chemiluminescence in peroxide reactions

被引：267
作者：
Adam, W
Kazakov, DV
Kazakov, VP
机构：
[1] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany
[2] Univ Puerto Rico, Dept Chem, Rio Piedras, PR 00931 USA
[3] RAS, Inst Organ Chem, Ufa Sci Ctr, Ufa 450054, Russia
来源：
CHEMICAL REVIEWS | 2005年 / 105卷 / 09期
关键词：
D O I：
10.1021/cr0300035
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An overview is given of the important role that 1O2 plays in the field of peroxide chemiluminescence (CL). In such chemiluminescent peroxide systems, either singlet oxygen acts as the direct emitter or it constitutes the oxidant to mediate light emission, presumably through an interdisciplinary dioxetane. The numerous light-generating systems are presented and their mechanisms scrutinized. Furthermore, the advantages of the CL method for singlet-oxygen detection and quantification are addressed. Focus is on reactions in which the singlet oxygen has been originally generated in the liquid phase.
引用
收藏
页码：3371 / 3387
页数：17
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