Plasmon-Enhanced Fluorescence and Spectral Modification in SHINEF

被引:57
作者
Aroca, Ricardo F. [1 ]
Teo, Geok Yi [1 ]
Mohan, Haider [1 ]
Guerrero, Ariel R. [1 ]
Albella, Pablo [2 ,3 ]
Moreno, Fernando [4 ]
机构
[1] Univ Windsor, Fac Sci, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada
[2] Ctr Fis Mat CSIC UPV EHU, Donostia San Sebastian 20018, Spain
[3] DIPC, Donostia San Sebastian 20018, Spain
[4] Univ Cantabria, Fac Ciencias, Grp Opt, Dept Fis Aplicada, Cantabria, Spain
基金
加拿大自然科学与工程研究理事会;
关键词
LANGMUIR-BLODGETT MONOLAYERS; SILVER; GROWTH;
D O I
10.1021/jp205997u
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Shell-isolated gold nanoparticles provide a reliable, portable, and efficient substrate for luminescence enhancement giving surface-enhanced fluorescence, termed SHINEF. The objectives of the present work are 2-fold: first, tuning the size of the gold core and the shell thickness for maximum SHINEF enhancement, and second, to use the shell isolated nanoparticles (SHINs) to demonstrate the spectral profile modification of the fluorescence spectrum. It is shown, using Langmuir-Blodgett monolayers of a dye with two distinct emissions (monomer and excimer), that the far field radiation of the nanostructure modulate the observed emission from the target fluorophore located in the near field zone of the nanostructure sustaining localized surface plasmon resonances (LSPR).
引用
收藏
页码:20419 / 20424
页数:6
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