Synthesis, structure, and properties of {N,N'-bis[2-(2-pyridyl)ethyl]pyridine-2,6-dicarboxamido}copper(II)

被引：72

作者：

Chavez, FA

Olmstead, MM

Mascharak, PK

机构：

[1] UNIV CALIF SANTA CRUZ,DEPT CHEM & BIOCHEM,SANTA CRUZ,CA 95064

[2] UNIV CALIF DAVIS,DEPT CHEM,DAVIS,CA 95616

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 05期

关键词：

D O I：

10.1021/ic9512136

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Cu(II) complex of N,N'-bis(2-(2-pyridyl)ethyl)-pyridine-2,6-dicarboxamide, a designed ligand with two amide moieties, has been isolated and structurally characterized. The copper center in this distorted square-pyramidal complex is coordinated to two deprotonated amido N donors and is situated 0.41 Angstrom above the mean basal plane. Such distortion results in a low A parallel to value of 154 G.

引用

页码：1410 / &

页数：4

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