Hydrogen peroxide oxidation of benzylic alcohols to benzaldehydes and benzoic acids under halide-free conditions

被引:88
作者
Sato, K
Takagi, J
Aoki, M
Noyori, R [1 ]
机构
[1] Nagoya Univ, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[2] Nagoya Univ, Math Sci Res Ctr, Chikusa Ku, Nagoya, Aichi 4648602, Japan
关键词
D O I
10.1016/S0040-4039(98)01642-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A series of benzaldehyde and benzoic acid derivatives can be obtained from benzylic alcohols by tungsten-catalyed oxidation with aqueous hydrogen peroxide under halide-free, aqueous/organic biphasic conditions. (C) 1998 Elsevier Science Ltd. All rights reserved.
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页码:7549 / 7552
页数:4
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