Unexpected formation of bis(1H-7-azaindol-3-yl)(2,4,5-trimethylphenyl)methane by erbium metal-induced C-H activation

被引：5

作者：

Deacon, GB ^{[1
]}

Junk, PC ^{[1
]}

Leary, SG ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2003年 / 345卷 / 9-10期

关键词：

catalysis; C-C bond formation; C-H activation; crystallography; erbium; lanthanide;

D O I：

10.1002/adsc.200303107

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Reaction of 7-azaindole (azinH) and 1,2,4,5-tetramethylbenzene (durene) in the presence of erbium metal and mercury at 170degreesC under vacuum induced an unusual C-C bond formation between a methyl group of durene and C3 of two azinH molecules yielding bis(H-7-azaindol-3-yl)(2,4,5-trimethylphenyl)methane 12: IUPAC name 3-[1H-pyrrolo[2,3-b]pyridin-3-yl(2,4,5-trimethylphe- nyl)methyl]-1H-pyrrolo[2,3-b]pyridine). The structure of 2 was established by X-ray crystallography and supported by IR, NMR and mass spectroscopy.

引用

页码：1115 / 1117

页数：3

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