Resolution of overlapping spectra by curve-fitting

被引：28

作者：

Hu, YG ^{[1
]}

Liu, JY

Li, W

机构：

[1] Wuhan Univ, Coll Elect Informat, Wuhan 430079, Peoples R China

[2] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China

[3] Univ New Mexico, Dept Elect & Comp Engn, Albuquerque, NM 87106 USA

来源：

ANALYTICA CHIMICA ACTA | 2005年 / 538卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

overlapping peaks; curve-fitting; resolving overlapping spectra; Gaussian function;

D O I：

10.1016/j.aca.2005.02.024

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

In this paper we present a novel method of curve-fitting based on Gaussian function, which is used to resolve the overlapping peaks. Correctly choosing the minimum separable peak-peak interval (MSI) is crucial for this type of problem. We propose a method that chooses appropriate MSI by analyzing the curve-fitting error changes with the MSI. The resolution of several kinds of overlapping peaks with computer-simulated noise has been performed and discussed in details. This method has been used for resolving of the UV-vis overlapping spectrum. The results are satisfactory and clearly show the effectiveness of the proposed method. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：383 / 389

页数：7

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