A structural and electrochemical study of some oxovanadium(IV) heterochelate complexes

被引：42

作者：

Chatterjee, M

Ghosh, S ^{[1
]}

Wu, BM

Mak, TCW

机构：

[1] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Calcutta 700032, W Bengal, India

[2] Chinese Univ Hong Kong, Dept Chem, Shatin, New Territories, Hong Kong

来源：

POLYHEDRON | 1998年 / 17卷 / 08期

关键词：

oxovanadium(IV)) heterochelates; structural study; dipicolinic acid ligand; electrochemical investigation;

D O I：

10.1016/S0277-5387(97)00282-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Physicochemical studies on two oxovanadium(IV) heterochelates involving the biologically active ONO donor ligand, dipicolinic acid (DPA) is reported. Structure of the complex [VO(DPA)(ophen)]. 3H(2)O has been determined and this led to the understanding of the geometry of the donor sites around the oxovanadium(IV) centre of other related complexes. Electrochemical behavior of the complexes were explored by cyclic voltammetry. (C) 1998 Elsevier Science Ltd. All rights reserved.

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页码：1369 / 1374

页数：6

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