Ring-opening polymerization of lactams. Living anionic polymerization and its applications

被引：125

作者：

Hashimoto, K ^{[1
]}

机构：

[1] Kogakuin Univ, Fac Engn, Dept Appl Chem, Tokyo 1920015, Japan

来源：

PROGRESS IN POLYMER SCIENCE | 2000年 / 25卷 / 10期

关键词：

living polymerization; proton transfer; polyamides; lactams; activated-monomer mechanism; polymerizability;

D O I：

10.1016/S0079-6700(00)00018-6

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Recent development in the held of the ring-opening polymerization of lactams is reviewed from the viewpoint of the living polymerization. The living anionic polymerization of several lactams has been attained by skillful selection of the monomer structure and the polymerization condition. The chemical modification of the acyllactam-type growing chain ends in the resulting monodisperse living polyamides is also described to be useful for the molecular design of various types of the well-defined and polyamide-composed polymeric materials. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：1411 / 1462

页数：52

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