Zinc cyanamide, Zn(CN2)

被引：69

作者：

Becker, M ^{[1
]}

Jansen, M ^{[1
]}

机构：

[1] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2001年 / 57卷 / 04期

关键词：

D O I：

10.1107/S0108270101000865

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single crystals of the title compound have been grown by annealing microcrystalline zinc cyanamide at 843 K in silver crucibles. Zn(CN2) crystallizes as colourless prisms. The crystal structure is composed of corner-linked ZnN4/2 tetrahedra. Carbon and nitrogen form (CN2)(2-) dumb-bells with the C atom on a twofold axis. Nitrogen is approximately trigonally planar, coordinated by two Zn atoms and one C atom.

引用

页码：347 / 348

页数：2

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