Cyclometalated palladium(II) fragments as building blocks in the construction of new heteronuclear metalomacrocycles

被引：66

作者：

López-Torres, M

Fernández, A

Fernández, JJ

Suárez, A

Castro-Juiz, S

Vila, JM ^{[1
]}

Pereira, MT

机构：

[1] Univ Santiago Compostela, Dept Quim Inorgan, Santiago De Compostela 15782, Spain

[2] Univ A Coruna, Dept Quim Fundamental, La Coruna 15071, Spain

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 07期

关键词：

D O I：

10.1021/om000840m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes [{(X)PdN(Cy) = C(H)C6H2C(H) = N(Cy)Pd(X)}(2){(mu Ph2PC5H4FeC5H4PPh2}(2)}(X = Cl (3), X = Br (4)) have been prepared by reaction of [(X)PdN(Cy) = C(H)C6H2C(H) = N(Cy)Pd(X)](n) (X = Cl (1), X = Br (2)) with 1,1'-bis(diphenylphosphino)ferrocene (dppf), and they were characterized by elemental analysis (C, H, N) and by H-1 and P-31{H-1} NMR spectroscopy in CDCl3. The compounds are arranged as hexanuclear supramolecular cages containing two different metals, palladium and iron. The crystal structure of complex 4 was determined by X-ray diffraction studies.

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页码：1350 / 1353

页数：4

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