Fluorescent Imidazolium-Based Cyclophane for Detection of Guanosine-5′-triphosphate and I- in Aqueous Solution of Physiological pH

被引：66

作者：

Ahmed, Nisar ^{[1
]}

Shirinfar, Bahareh ^{[1
]}

Geronimo, Inacrist ^{[1
]}

Kim, Kwang S. ^{[1
]}

机构：

[1] Pohang Univ Sci & Technol, Dept Chem, Ctr Superfunct Mat, Pohang 790784, South Korea

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 20期

关键词：

ANION RECOGNITION; SELECTIVE RECOGNITION; SENSOR; CHEMOSENSOR; RECEPTOR; LUMINESCENT; INCLUSION; RESONANCE; DESIGN; DRIVEN;

D O I：

10.1021/ol202183t

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new water-soluble and fluorescent imidazollum-anthracene cyclophane (1) effectively recognizes the biologically Important GTP and I- over other anions in a 100% aqueous solution of physiological pH 7.4. Fluorescence and H-1 NMR spectra and ab initio calculations demonstrate that emission arises from the formation of an excimer state and quenching occurs upon GTP/I- binding through (C-H)(+)center dot center dot center dot A(-) hydrogen bond interactions.

引用

页码：5476 / 5479

页数：4

共 59 条

[1] cyclo-Bis(urea-3,6-dichlorocarbazole) as a Chromogenic and Fluorogenic Receptor for Anions and a Selective Sensor of Zinc and Copper Cations [J].

Ahmed, Nisar ;

Geronimo, Inacrist ;

Hwang, In-Chul ;

Singh, N. Jiten ;

Kim, Kwang S. .

CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (31) :8542-8548

[2]

Alberts B., 2002, The shape and structure of proteins, Vfourth, DOI 10.1093/aob/mcg023

[3]

Beer PD, 2001, ANGEW CHEM INT EDIT, V40, P486, DOI 10.1002/1521-3773(20010202)40:3<486::AID-ANIE486>3.0.CO

[4]

2-P

[5] Metal-organic anion receptors: Arranging urea hydrogen-bond donors to encapsulate sulfate ions [J].

Bondy, CR ;

Gale, PA ;

Loeb, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (16) :5030-5031

[6]

Cafeo G., 2000, ANGEW CHEM, V112, P1556

[7] Luminescent sensors and switches in the early 21st century [J].

Callan, JF ;

de Silva, AP ;

Magri, DC .

TETRAHEDRON, 2005, 61 (36) :8551-8588

[8] A calix[4]imidazolium[2]pyridine as an anion receptor [J].

Chellappan, K ;

Singh, NJ ;

Hwang, IC ;

Lee, JW ;

Kim, KS .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (19) :2899-2903

[9] 1,8-diamino-3,6-dichlorocarbazole: A promising building block for anion receptors [J].

Chmielewski, MJ ;

Charon, M ;

Jurczak, J .

ORGANIC LETTERS, 2004, 6 (20) :3501-3504

[10] A new fluoride selective fluorescent as well as chromogenic chemosensor containing a naphthalene urea derivative [J].

Cho, EJ ;

Moon, JW ;

Ko, SW ;

Lee, JY ;

Kim, SK ;

Yoon, J ;

Nam, KC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (41) :12376-12377

← 1 2 3 4 5 6 →