The first structurally characterized discrete dinuclear μ-cyano hexacyanoferrate complex

被引：62

作者：

Bernhardt, PV

Martinez, M ^{[1
]}

机构：

[1] Univ Queensland, Dept Chem, Brisbane, Qld 4072, Australia

[2] Univ Barcelona, Dept Quim Organ, E-08028 Barcelona, Spain

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 03期

关键词：

D O I：

10.1021/ic981019u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mixed valence complexes containing ferro- and ferricyanide have been known for almost 300 years, but no dinuclear, non-polymeric examples of these complexes have been structurally characterized. Here we report the first such example, comprising ferrocyanide coordinated to a pentaaminecobalt(III) complex. This Fe-II-Co-III complex may be reversibly oxidized to the Fe-III-Co-III analogue.

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页码：424 / +

页数：3

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