Living ring-opening polymerization of lactones using cationic zirconocene complex catalysts

被引：51

作者：

Hayakawa, M ^{[1
]}

Mitani, M ^{[1
]}

Yamada, T ^{[1
]}

Mukaiyama, T ^{[1
]}

机构：

[1] SCI UNIV TOKYO, FAC SCI, DEPT APPL CHEM, SHINJUKU KU, TOKYO 162, JAPAN

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 1997年 / 198卷 / 05期

关键词：

D O I：

10.1002/macp.1997.021980502

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Living cationic ring-opening polymerization of epsilon-caprolactone (CL), delta-valerolactone (VL) and 1,3-dioxepane-2-one (6) was achieved at room temperature by using zirconocene berate complex catalysts. Respective block copolymerization of CL with VL or with cyclic carbonate 6 was also successfully performed. The mechanism of the present cationic living polymerization is discussed.

引用

页码：1305 / 1317

页数：13

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