Crystals and life

被引:62
作者
Arrhenius, GO [1 ]
机构
[1] Univ Calif San Diego, Scripps Inst Oceanog, La Jolla, CA 92093 USA
关键词
D O I
10.1002/hlca.200390135
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The record of life's emergence on Earth has been thoroughly obliterated by the remelting and turnover of the crust, soggy and pliable from the water, retained by the planet's gravitational field. Provided that life existed on a smaller body such as Mars with an arrested crustal evolution, a protected sedimentary record there may give clues to the decisive events in the first 500 million years in the history of our solar system. Until such records become available, we have in our guesswork to rely on laboratory constructions that need to satisfy the demands both of chemical feasibility and environmental boundary conditions. The combination leaves few survivors among competing hypotheses. As life entails a decrease in entropy and creation of order, the origin and propagation of crystalline order has become a guiding theoretical concept. Recognizing Jack Dunitz's fundamental contribution to this field of knowledge, I wish to dedicate my modest discourse to this great scientist upon his scoring of the fourth significant time mark on the staff of life.
引用
收藏
页码:1569 / 1586
页数:18
相关论文
共 68 条
  • [1] ALLMANN R, 1970, CHIMIA, V24, P99
  • [2] Allmann R., 1968, NEUES JB MINER MONAT, P140
  • [3] Entropy and charge in molecular evolution - the case of phosphate
    Arrhenius, G
    Sales, B
    Mojzsis, S
    Lee, T
    [J]. JOURNAL OF THEORETICAL BIOLOGY, 1997, 187 (04) : 503 - 522
  • [4] Glycolonitrile oligomerization: Structure of isolated oxazolines, potential heterocycles on the early earth
    Arrhenius, G
    Baldridge, KK
    RichardsGross, S
    Siegel, JS
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (16) : 5522 - 5525
  • [5] ARRHENIUS G, 1993, ST CHEM EVOL & ORIG, P25
  • [6] Accretion of Moon and Earth and the emergence of life
    Arrhenius, G
    Lepland, A
    [J]. CHEMICAL GEOLOGY, 2000, 169 (1-2) : 69 - 82
  • [7] ARRHENIUS G, 2002, FUNDAMENTALS LIFE, P203
  • [8] ARCHEAN GEOCHEMISTRY OF FORMALDEHYDE AND CYANIDE AND THE OLIGOMERIZATION OF CYANOHYDRIN
    ARRHENIUS, T
    ARRHENIUS, G
    PAPLAWSKY, W
    [J]. ORIGINS OF LIFE AND EVOLUTION OF THE BIOSPHERE, 1994, 24 (01): : 1 - 17
  • [9] BERNAL JD, 1947, P PHYS SOC LOND, V62, P537
  • [10] Bernal JD, 1959, CLAY MINERALS B, V4, P15