Unprecedented homochiral olefin-copper(I) 2D coordination polymer grid based on chiral ammonium salts as building blocks

被引：29

作者：

Xie, YR

Wang, XS

Zhao, H

Zhang, J

Weng, LH

Duan, CY

Xiong, RG ^{[1
]}

You, XZ

Xue, ZL

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

[3] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 22期

关键词：

D O I：

10.1021/om034077i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

4-Vinylbenzylcinchonidinium chloride ([VB-N-CIN]Cl; 1), prepared from the corresponding cinchona alkaloid and 4-vinylbenzyl chloride in refluxing acetone and N,N-dimethylformamide, solvothermally reacts with (CuCl)-Cl-I to afford the unprecedented 2D homochiral copper(I)-olefin coordination polymer Cu5Cl6(VB-N-CIN)(2).C2H5OH (2.EtOH) with a 2D layered network. A preliminary enantioseparation investigation shows that the 2D layered network in 2 is capable of selectively intercalating (R)-2-butanol.

引用

页码：4396 / 4398

页数：3

共 29 条

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[2]

2-X

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