An unusual mixed-guest inclusion compound. Crystal structures of the host compound hexakis(3-hydroxy-3,3-diphenylprop-2ynyl)benzene, and its inclusion compound with acetonitrile and benzene

被引：5

作者：

Bourne, SA ^{[1
]}

Nash, KLG

Toda, F

机构：

[1] Univ Cape Town, Dept Chem, ZA-7701 Rondebosch, South Africa

[2] Ehime Univ, Fac Engn, Dept Appl Chem, Matsuyama, Ehime 790, Japan

来源：

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY | 1998年 / 32卷 / 01期

关键词：

hexapedal host; alpha-phase; mixed guest inclusion compound;

D O I：

10.1023/A:1007946923878

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structures of the alpha-phase of hexakis(3-hydroxy-3,3-diphenylprop-2-ynyl)benzene (1), and its inclusion compound with acetonitrile and benzene (2) have been determined by single crystal diffraction. 2 was further characterised by nuclear magnetic resonance spectroscopy, and thermal analysis. The inclusion of benzene by this host appears to depend on the presence of acetonitrile.

引用

页码：91 / 102

页数：12

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