Organometallic polymers containing coordinatively saturated platinum(II) complexes as pendants

被引:6
作者
Panunzi, B
Roviello, A
Ruffo, F
Vivo, A
机构
[1] Univ Naples, Dipartimento Chim, I-80134 Naples, Italy
[2] Univ Naples Federico II, Dipartimento Sci Alimenti, I-80055 Portici, Na, Italy
关键词
platinum complexes; five-coordination complexes; polymeric complexes;
D O I
10.1016/S0020-1693(98)00157-1
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis and some properties of soluble organometallic polymers which contain trigonal bipyramidal platinum(II) complexes as pendants are described. An N,N-chelate and an olefin define the equatorial plane of the complex, while two anionic ligands, or one anion and a pyridine nitrogen, occupy the axial positions. Each of the coordination sites was used to anchor the organometallic fragment to the polymeric chain. (C) 1998 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:141 / 147
页数:7
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