Towards a mechanistic insight into the Julia-Colonna asymmetric epoxidation of α, β-unsaturated ketones using discrete lengths of poly-leucine.

被引：33

作者：

Bentley, PA ^{[1
]}

Cappi, MW

Flood, RW

Roberts, SM

Smith, JA

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 3BX, Merseyside, England

[2] Univ Liverpool, Sch Biol Sci, Liverpool L69 3BX, Merseyside, England

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 50期

基金：

英国生物技术与生命科学研究理事会; 英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/S0040-4039(98)02090-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Accurate length poly-leucines have been used to evaluate mechanistic features of the asymmetric epoxidation of chalcone. Studies have been directed towards the influence of the length of the chain, the stereochemistry of the amino acid residues and the nature of the terminal amino group. (C) 1998 Elsevier Science Ltd, All rights reserved.

引用

页码：9297 / 9300

页数：4

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