Organized mesoporous TiO2 films exhibiting greatly enhanced performance in dye-sensitized solar cells

被引:489
作者
Zukalová, M
Zukal, A
Kavan, L
Nazeeruddin, MK
Liska, P
Grätzel, M
机构
[1] Acad Sci Czech Republ, J Heyrovsky Inst Phys Chem, CZ-18223 Prague, Czech Republic
[2] Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland
关键词
D O I
10.1021/nl051401l
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Pluronic P123 templated mesoporous TiO2 film was grown via layer-by-layer deposition and characterized by a novel methodology based on the adsorption of n-pentane. Multiple-layer depositions did not perturb the mesoporous structure significantly. Our TiO2 film was sensitized by a newly developed Ru-bipyridine dye (N945) and was applied as a photoanode in dye-sensitized solar cell. The 1-mu m-thick mesoporous film, made by the superposition of three layers, showed enhanced solar conversion efficiency by about 50% compared to that of traditional films of the same thickness made from randomly oriented anatase nanocrystals.
引用
收藏
页码:1789 / 1792
页数:4
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