Transformation of ethanolamine to diazabicyclo[2.2.2]octane over MFI zeolite

被引：10

作者：

Bhat, YS ^{[1
]}

Das, J ^{[1
]}

Ali, S ^{[1
]}

Bhatt, BD ^{[1
]}

Halgeri, AB ^{[1
]}

机构：

[1] INDIAN PETROCHEM CORP LTD,RES CTR,BARODA 391346,GUJARAT,INDIA

来源：

APPLIED CATALYSIS A-GENERAL | 1996年 / 148卷 / 01期

关键词：

ethanolamine; DABCO; MFI zeolite;

D O I：

10.1016/S0926-860X(96)00272-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The conversion of ethanolamine to industrially important diazabicyclo [2.2.2] octane (DABCO) has been studied over the ZSM-5 zeolite. This transformation takes place via the piperazine route. With the increase in reaction temperature from 325 to 400 degrees C, ethanolamine conversion increased from 4.5 to 82%, while the DABCO selectivity decreased from 71 to 47%. The catalyst stability is lower at higher ethanolamine conversion, while it improves at lower ethanolamine conversion.

引用

页码：L1 / L6

页数：6