Photoacoustic soot sensor for in-situ black carbon monitoring

The PhotoAcoustic Soot Sensor (PASS) for in situ black carbon mass monitoring is presented. The sensor combines a high-power laser diode (lambda = 802 nm; P = 450 mW) and a novel spectrophone setup to achieve a portable sensor system for black carbon measurements. The acoustic resonator with a Q-factor of approximate to 300 is operated in its 2nd azimuthal mode at 6670 Hz. To estimate the effects of the window position, laser beam collimation, and different loss mechanisms on spectrophone sensitivity a model treating these effects with respect to the signal strength of the azimuthal modes is described. It gives a cell constant of 5.8 V/(W m(-1)) in good agreement with 5.9 V/(W m(-1)) obtained from measurements with particulate carbon. Additionally, this model permits a method for an absolute calibration of the spectrophone. To improve the signal-to-noise ratio, the photoacoustic signal is estimated by a weighted least-squares fit to an averaged line profile of the excited normal mode instead of a direct measurement of peak height. Finally, the application of this data processing algorithm yields a detection limit of 1.5 x 10(-6) m(-1) or 0.5 mu g black carbon per m(3).