Ionic radius of (CF3SO2C- and applicability of Stokes law to its propylene carbonate solution

被引：36

作者：

Ue, M

机构：

[1] Mitsubishi Chemical Corporation, Tsukuba Research Center, Ami, Inashiki, Ibaraki 300-03

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1996年 / 143卷 / 11期

关键词：

D O I：

10.1149/1.1837231

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The ionic radius of (CF3SO2C- was calculated to be 0.375 nm from its van der Waals volume, which was obtained by molecular mechanics calculations with the aid of its crystallogaphic data. This radius was correlated with its single ion limiting molar conductivity in propylene carbonate at 25 degrees C, and it was proven that this anion also nearly follows the behavior of perfect slip in Stokes law, as is observed for other popular anions for lithium battery applications.

引用

页码：L270 / L272

页数：3

共 24 条

[1]

Armand M., 1990, 2 INT S POL EL, P91

[2] VAN DER WAALS VOLUMES + RADII [J].