Chain extension of aldonolactones by samarium iodide mediated Dreiding-Schmidt reactions and samarium assisted Imamoto reactions

被引：15

作者：

Csuk, R ^{[1
]}

Horing, U ^{[1
]}

Schaade, M ^{[1
]}

机构：

[1] UNIV HEIDELBERG,PHARM CHEM INST,D-69120 HEIDELBERG,GERMANY

来源：

TETRAHEDRON | 1996年 / 52卷 / 29期

关键词：

D O I：

10.1016/0040-4020(96)00508-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Unprecedented SmI2 mediated Dreiding-Schmidt reactions were used for chain extension reactions of aldonolactones with alkyl 2-bromomethyl acrylates or 2-bromomethyl-acrylonitrile, respectively. The reaction of aldonolactones with diiodomethane in the presence of samarium powder resulted in the formation of polyhydroxyalkyl substituted cyclopropanols. Copyright (C) 1996 Elsevier Science Ltd.

引用

页码：9759 / 9776

页数：18

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