Polyguanidines as Chiral Orienting Media for Organic Compounds

被引：51

作者：

Arnold, Lena ^{[1
]}

Marx, Andreas ^{[1
]}

Thiele, Christina M. ^{[1
]}

Reggelin, Michael ^{[1
]}

机构：

[1] Tech Univ Darmstadt, Clemens Schopf Inst Organ Chem & Biochem, D-64287 Darmstadt, Germany

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 34期

关键词：

alignment media; liquid crystals; NMR spectroscopy; polyguanidines; RESIDUAL DIPOLAR COUPLINGS; LIQUID-CRYSTALLINE PROPERTIES; SENSE-SELECTIVE POLYMERIZATION; NMR ALIGNMENT MEDIA; BENZYL-L-GLUTAMATE; HELIX-SENSE; RELATIVE CONFIGURATION; DEUTERIUM NMR; ORIENTATIONAL PROPERTIES; LIVING POLYMERIZATION;

D O I：

10.1002/chem.201000940

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Handy polymers: The lyotropic liquidcrystalline phases of helically chiral polyguanidines are proposed as new chiral orienting media for organic compounds. The enantiomers of isopinocampheol (IPC) are oriented in an enantiodifferentiating manner (see figure). The difference in orientation induced for the two enantiomers seems to be larger than the one observed in poly-γ-benzyl-L-glutamate (PBLG). © 2010 Willey-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10342 / 10346

页数：5

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