Quantitative dynamic interconversion between AgI-mediated capsule and cage complexes accompanying guest encapsulation/release

被引：96

作者：

Hiraoka, S

Harano, K

Shiro, M

Shionoya, M ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Tokyo 1130033, Japan

[2] Rigaku Corp, Akishima, Tokyo 1968666, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 18期

关键词：

cage compounds; host-guest systems; molecular recognition; self-assembly; silver;

D O I：

10.1002/anie.200462394

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) An accommodating host: Capsule- and cage-shaped complexes are formed from AgI and disk-shaped trismonodentate ligands in 1:1 and 1.5:1 concentration ratios, respectively; their interconversion is reversible. The capsule complex can entrap a small neutral molecule such as adamantane in the inner space, but the guest is released when the cage structure is adopted. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2727 / 2731

页数：5

共 58 条

[1]

[Anonymous], ANGEW CHEM

[2] Quantitative formation of coordination nanotubes templated by rodlike guests [J].