A new bifunctional para-toluenesulfonamidophenanthroline-aminoquinoline ligand. Synthesis and characterisation of the corresponding Ru(II) complex

被引：4

作者：

Del Guerzo, A

Demeunynck, M

Lhomme, J

Kirsch-De Mesmaeker, A

机构：

[1] Univ Grenoble 1, CNRS, UMR 5616, LEDSS, F-38041 Grenoble, France

[2] Free Univ Brussels, B-1050 Brussels, Belgium

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1998年 / 1卷 / 09期

关键词：

ruthenium complexes; bifunctional complexes; DNA photoprobes;

D O I：

10.1016/S1387-7003(98)00092-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and characterisation of a new bifunctional Ru(II) complex are presented. This compound contains a metallic unit, photoreactive versus the guanines of DNA, and a new bifunctional ligand. An intramolecular luminescence quenching makes this complex an attractive candidate for photoprobing DNA where the intramolecular quenching process is inhibited with restoration of luminescence. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：339 / 342

页数：4

共 7 条

[1] Photophysics of bifunctional Ru(II) complexes bearing an aminoquinoline organic unit. Potential new photoprobes and photoreagents of DNA [J].