Oxidation/reduction interconversion of thiols and disulfides using hydrogen and oxygen catalyzed by a rhodium complex

被引:37
作者
Arisawa, M [1 ]
Sugata, C [1 ]
Yamaguchi, M [1 ]
机构
[1] Tohoku Univ, Grad Sch Pharmaceut Sci, Dept Organ Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan
基金
日本学术振兴会;
关键词
D O I
10.1016/j.tetlet.2005.06.169
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
RhH(PPh3)(4) catalyzes reduction of disulfides to thiols by hydrogen and RhH(PPh3)(4)/1,4-bis(diphenylphosphino)butane (dppb) catalyzes oxidation of thiols to disulfides by oxygen. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:6097 / 6099
页数:3
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