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Electrochemistry of phenyl-N-capped aniline oligomers. Evaluation of optical and electrochemical properties of ideal polyaniline

被引：29
作者：
DAprano, G
Leclerc, M
Zotti, G
机构：
[1] CNR,IST POLAROG & ELETTROCHIM PREPARAT,I-35020 PADUA,ITALY
[2] MAX PLANCK INST POLYMER RES,D-55021 MAINZ,GERMANY
[3] UNIV MONTREAL,DEPT CHIM,MONTREAL,PQ H3C 3J7,CANADA
来源：
SYNTHETIC METALS | 1996年 / 82卷 / 01期
基金：
加拿大自然科学与工程研究理事会;
关键词：
polyaniline; phenyl-N-capped aniline oligomers; electrochemical properties; optical properties;
D O I：
10.1016/S0379-6779(97)80010-0
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Potentials for the first reversible oxidation and optical bandgaps of phenyl-N-capped aniline oligomers (n = 1, 2 and 4) are linearly related with 1/n. The comparison of the values extrapolated for the infinitely long polymer and those of electrochemically synthesized polymer samples indicates for the latter an average equivalent length of 6-10 monomeric units.
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页码：59 / 61
页数：3
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