Electronic structure of noncrystalline transition metal silicate and aluminate alloys

A localized molecular orbital description (LMO) for the electronic states of transition metal (TM) noncrystalline silicate and aluminate alloys establishes that the lowest conduction band states are derived from d states of TM atoms. The relative energies of these states are in agreement with the LMO approach, and have been measured by x-ray absorption spectroscopy for ZrO2-SiO2 alloys, and deduced from an interpretation of capacitance-voltage and current-voltage data for capacitors with Al2O3-Ta2O5 allot dielectrics. The LMO model yields a scaling relationship for band offset energies providing a guideline for selection of gate dielectrics for advanced Si devices. (C) 2001 American Institute of Physics.