The dynamics in dodecane/C10E5/water microemulsions determined by time resolved scattering techniques

被引:46
作者
Hellweg, T [1 ]
Langevin, D
机构
[1] TU Chemnitz, Inst Phys Mat Forsch & Flussigkeiten, D-09107 Chemnitz, Germany
[2] CNRS, Ctr Rech Paul Pascal, F-33600 Pessac, France
关键词
NSE; DLS; microemulsions; bending elasticity; viscosity of the interior;
D O I
10.1016/S0378-4371(98)00461-0
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Recently, an alternative approach to the determination of the bending elastic constants of the surfactant film in droplet microemulsions was developed, which is based on a combination of neutron spin-echo spectroscopy (NSE) and dynamic light scattering (DLS). In this work the approach will be applied to investigate another C10E5-based microemulsion containing the oil n-dodecane. The determined values for kappa and <(kappa)over bar> compare well to values determined for the n-octane containing system. Small-angle neutron scattering (SANS) data will also be presented and discussed. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:370 / 387
页数:18
相关论文
共 41 条
[1]   Microstructure in a ternary microemulsion studied by small angle neutron scattering [J].
BaggerJorgensen, H ;
Olsson, U ;
Mortensen, K .
LANGMUIR, 1997, 13 (06) :1413-1421
[2]  
BASSEREAU P, 1992, J PHYS II, V2, P1257
[3]  
Berne B.J., 2000, DOVER BOOKS PHYS SER
[4]   EFFECTS OF ALKANE CHAIN-LENGTH ON THE BENDING ELASTICITY CONSTANT-K OF AOT MONOLAYERS AT THE PLANAR OIL-WATER INTERFACE [J].
BINKS, BP ;
KELLAY, H ;
MEUNIER, J .
EUROPHYSICS LETTERS, 1991, 16 (01) :53-58
[5]   MEASUREMENT OF FILM RIGIDITY AND INTERFACIAL-TENSIONS IN SEVERAL IONIC SURFACTANT OIL-WATER MICROEMULSION SYSTEMS [J].
BINKS, BP ;
MEUNIER, J ;
ABILLON, O ;
LANGEVIN, D .
LANGMUIR, 1989, 5 (02) :415-421
[6]  
BOLTENHAGEN P, 1991, J PHYS II, V1, P1233, DOI 10.1051/jp2:1991130
[7]   CURVATURE AS A DETERMINANT OF MICROSTRUCTURE AND MICROEMULSIONS [J].
CHEN, SJ ;
EVANS, DF ;
NINHAM, BW ;
MITCHELL, DJ ;
BLUM, FD ;
PICKUP, S .
JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (05) :842-847
[8]  
Cotton J.P., 1991, Neutron, X-Ray and Light Scattering
[9]   MICRO-EMULSIONS AND THE FLEXIBILITY OF OIL-WATER INTERFACES [J].
DEGENNES, PG ;
TAUPIN, C .
JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (13) :2294-2304
[10]   SHAPE AND SIZE FLUCTUATIONS OF MICROEMULSION DROPLETS - THE ROLE OF COSURFACTANT [J].
FARAGO, B ;
RICHTER, D ;
HUANG, JS ;
SAFRAN, SA ;
MILNER, ST .
PHYSICAL REVIEW LETTERS, 1990, 65 (26) :3348-3351