A Low-Energy-Gap Organic Dye for High-Performance Small-Molecule Organic Solar Cells

被引：221

作者：

Lin, Li-Yen ^{[2
]}

Chen, Yi-Hong ^{[1
]}

Huang, Zheng-Yu ^{[1
]}

Lin, Hao-Wu ^{[1
]}

Chou, Shu-Hua ^{[2
]}

Lin, Francis ^{[2
]}

Chen, Chang-Wen ^{[1
]}

Liu, Yi-Hung ^{[2
]}

Wong, Ken-Tsung ^{[2
]}

机构：

[1] Natl Tsing Hua Univ, Dept Mat Sci & Engn, Hsinchu 30013, Taiwan

[2] Natl Taiwan Univ, Dept Chem, Taipei 10617, Taiwan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 40期

关键词：

INTERNAL CHARGE-TRANSFER; THIN-FILMS; EFFICIENT; PHOTOVOLTAICS;

D O I：

10.1021/ja205126t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel donor-acceptor-acceptor (D-A-A) donor molecule, DTDCTB, in which an electron-donating ditolylaminothienyl moiety and an electron-withdrawing dicyanovinylene moiety are bridged by another electron-accepting 2,1,3-benzothiadiazole block, has been synthesized and characterized. A vacuum-deposited organic solar cell employing DTDCTB combined with the electron acceptor C-70 achieved a record-high power conversion efficiency (PCE) of 5.81%. The respectable PCE is attributed to the solar spectral response extending to the near-IR region and the ultracompact absorption dipole stacking of the DTDCTB thin film.

引用

页码：15822 / 15825

页数：4

共 41 条

[1] Synthesis of Conjugated Polymers for Organic Solar Cell Applications [J].

Cheng, Yen-Ju ;

Yang, Sheng-Hsiung ;

Hsu, Chain-Shu .

CHEMICAL REVIEWS, 2009, 109 (11) :5868-5923

[2] Bulk Heterojunction Solar Cells Using Thieno[3,4-c]pyrrole-4,6-dione and Dithieno[3,2-b:2′,3′-d]silole Copolymer with a Power Conversion Efficiency of 7.3% [J].

Chu, Ta-Ya ;

Lu, Jianping ;

Beaupre, Serge ;

Zhang, Yanguang ;

Pouliot, Jean-Remi ;

Wakim, Salem ;

Zhou, Jiayun ;

Leclerc, Mario ;

Li, Zhao ;

Ding, Jianfu ;

Tao, Ye .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (12) :4250-4253

[3]

Coffin RC, 2009, NAT CHEM, V1, P657, DOI [10.1038/NCHEM.403, 10.1038/nchem.403]

[4] Light-emitting organic solar cells based on a 3D conjugated system with internal charge transfer [J].

Cravino, Antonio ;

Leriche, Philippe ;

Aleveque, Olivier ;

Roquet, Sophie ;

Roncali, Jean .

ADVANCED MATERIALS, 2006, 18 (22) :3033-+

[5] Modelling the optical constants of organic thin films: impact of the choice of objective function [J].

Djurisic, AB ;

Fritz, T ;

Leo, K .

JOURNAL OF OPTICS A-PURE AND APPLIED OPTICS, 2000, 2 (05) :458-464

[6] Efficient organic solar cells based on a double p-i-n architecture using doped wide-gap transport layers -: art. no. 244102 [J].

Drechsel, J ;

Männig, B ;

Kozlowski, F ;

Pfeiffer, M ;

Leo, K ;

Hoppe, H .

APPLIED PHYSICS LETTERS, 2005, 86 (24) :1-3

[7]

EVANS R, 2010, Patent No. 132952

[8] Dicyanovinyl-Substituted Oligothiophenes: Structure-Property Relationships and Application in Vacuum-Processed Small-Molecule Organic Solar Cells [J].

Fitzner, Roland ;

Reinold, Egon ;

Mishra, Amaresh ;

Mena-Osteritz, Elena ;

Ziehlke, Hannah ;

Koerner, Christian ;

Leo, Karl ;

Riede, Moritz ;

Weil, Matthias ;

Tsaryova, Olga ;

Weiss, Andre ;

Uhrich, Christian ;

Pfeiffer, Martin ;

Baeuerle, Peter .

ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (05) :897-910

[9]

HIROSHI H, 2009, ADV FUNCT MATER, V19, P3948

[10] Development of New Conjugated Polymers with Donor-π-Bridge-Acceptor Side Chains for High Performance Solar Cells [J].

Huang, Fei ;

Chen, Kung-Shih ;

Yip, Hin-Lap ;

Hau, Steven K. ;

Acton, Orb ;

Zhang, Yong ;

Luo, Jingdong ;

Jen, Alex K. -Y. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (39) :13886-+

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