CO2 fixation and activation by metal complexes of small polyazacyclophanes

被引:14
作者
Andrés, S
Escuder, B
Doménech, A
García-España, E
Luis, SV
Marcelino, V
Llinares, JM
Ramírez, JA
Soriano, C
机构
[1] Univ Valencia, Fac Quim, Dept Quim Inorgan, E-46100 Burjassot, Valencia, Spain
[2] Univ Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12080, Spain
[3] Univ Valencia, Fac Quim, Dept Quim Anal, E-46100 Burjassot, Valencia, Spain
[4] Univ Kansas, Dept Chem, Lawrence, KS 66045 USA
[5] Univ Valencia, Fac Farm, Dept Quim Organ, Burjassot 46100, Spain
关键词
azacyclophanes; carbon dioxide; Cu2+ coordination; Zn2+ coordination; electrocatalysis;
D O I
10.1002/poc.400
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The interaction of the cyclophanes 2,6,9,13-tetraaza[14]paracyclophane (L1) and 2,6,9,13-tetraaza[14]metacyclophane (L2) and of their Zn2+ and Cu2+ complexes with CO32- and its protonated forms is described. The actuation of the Cu2+-L2 system as an electrocatalyst for the reduction of CO2 to CO in water is advanced. Copyright (C) 2001 John Wiley & Sons, Ltd.
引用
收藏
页码:495 / 500
页数:6
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