Studies on electrical transport properties of a novel n-type polymer containing tripylborane and fluorene moieties

被引：26

作者：

Sato, N ^{[1
]}

Ogawa, H

Matsumoto, E

Chujo, Y

Matsuyama, T

机构：

[1] Kyoto Univ, Inst Res Reactor, Osaka 5900494, Japan

[2] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Kyoto 6068510, Japan

来源：

SYNTHETIC METALS | 2005年 / 154卷 / 1-3期

关键词：

conjugated polymers; conducting polymers; transport measurements; photoconductivity;

D O I：

10.1016/j.synthmet.2005.07.029

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

An organoboron polymer, poly[ (2,4,6-triisopropylphenyl)borylenevinylene-2,7-fluorenylenevinylene], has been synthesized by hydroboration polymerization with 2,4,6-triisopropylphenylborane and 2,7-diethynylfluorene. The polymer is pi-electron deficient due to boron atom contained in its main-chain and the pi-conjugation length in it is extended via the vacant p-orbital of the boron atom. It has been found that the polymer shows an electrical conductivity of about 10(6) Scm(-1) by n-cloping with triethylamine at RT. By continuous photo-excitation of ITO-Polymer-Au cells, it has been proved that the polymer is an n-type conductor. In addition, by pulsed photo-excitation of the cell, it has been verified that the drift mobility of electron is about five times higher than that of hole. The n-type electrical transport properties of the polymer have been also associated with an anodic wave that appears at about -1.17V in cyclic voltammograms and is ascribable to n-doping.

引用

页码：113 / 116

页数：4

共 3 条

[1] Electrical conductivity of π-conjugated organoboron polymers upon n-type doping [J].