Redox-switching of nonlinear optical behavior in Langmuir-Blodgett thin films containing a ruthenium(II) ammine complex

被引：131

作者：

Boubekeur-Lecaque, Leila ^{[1
]}

Coe, Benjamin J. ^{[1
]}

Clays, Koen ^{[2
]}

Foerier, Stijn ^{[2
]}

Verbiest, Thierry ^{[2
]}

Asselberghs, Inge ^{[2
]}

机构：

[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

[2] Univ Louvain, Dept Chem, B-3001 Louvain, Belgium

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 11期

关键词：

D O I：

10.1021/ja711170q

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alternating Langmuir-Blodgett multilayers containing a metal-to-ligand charge-transfer chromophore based on (Ru-II(NH3)(5))(2+) show redox-switching of the second harmonic generation from a 1064 nm laser.

引用

页码：3286 / +

页数：3

共 29 条

[1] Langmuir-Blodgett films: molecular engineering of non-centrosymmetric structures for second-order nonlinear optical applications [J].

Ashwell, GJ .

JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (09) :1991-2003

[2] Switching of molecular second-order polarisability in solution [J].

Asselberghs, I ;

Clays, K ;

Persoons, A ;

Ward, MD ;

McCleverty, J .

JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (19) :2831-2839

[3]

ASSELBERGHS L, 2005, P SPIE INT SOC OPT E, V5935

[4] Aggregation of amphiphilic squaraines at the air-water interface and in Langmuir-Blodgett films [J].

Chen, HJ ;

Law, KY ;

Whitten, DG .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (14) :5949-5955

[5] Synthesis, characterization, Langmuir-Blodgett film-forming properties, and second-harmonic-generation studies of ruthenium(II) complexes with long hydrocarbon chains [J].

Chu, BWK ;

Yam, VWW .

INORGANIC CHEMISTRY, 2001, 40 (14) :3324-3329

[6]

Coe B. J., 2004, COMPREHENSIVE COORDI, V9, P621

[7] Switchable nonlinear optical metallochromophores with pyridinium electron acceptor groups [J].

Coe, Benjamin J. .

ACCOUNTS OF CHEMICAL RESEARCH, 2006, 39 (06) :383-393

[8]

Coe BJ, 1999, CHEM-EUR J, V5, P2464, DOI 10.1002/(SICI)1521-3765(19990903)5:9<2464::AID-CHEM2464>3.0.CO

[9]

2-L

[10]

Coe BJ, 2002, J PHYS CHEM A, V106, P897, DOI [10.1021/jp012320q, 10.1021/jp0123210q]

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