NMR techniques for the investigation of solvation phenomena and non-covalent interactions

被引：103

作者：

Bagno, A

Rastrelli, F

Saielli, G

机构：

[1] Univ Padua, Dipartimento Sci Chim, I-35131 Padua, Italy

[2] CNR, Ist Tecnol Membrane, Sez Padova, I-35131 Padua, Italy

来源：

PROGRESS IN NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY | 2005年 / 47卷 / 1-2期

关键词：

solvent effect; non-covalent interactions; chemical shift; spin-spin coupling; computational chemistry; intermolecular NOE; spin-lattice relaxation; diffusion coefficients;

D O I：

10.1016/j.pnmrs.2005.08.001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The solvation phenomena and non-covalent interactions were investigated using NMR techniques. The solvation phenomena and related non-covalent interactions invariably lead to physico-chemical changes in the whole solute-solvent system. It enables to investigate changes in geometry, electronic structure and molecular dynamics. The results show that the degree of understanding of solvation phenomena by NMR was high because the interpretation can often dipense with empirical considerations.

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页码：41 / 93

页数：53

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